Answer:
it contains 11 electrons
Explanation:
What are the n, l, and possible ml values for the 2p and 5f sublevels?
The 2p sublevel has quantum numbers n=2, l=1, and possible ml values of -1, 0, +1, with a maximum of 6 electrons. The 5f sublevel has quantum numbers n=5, l=3, and possible ml values ranging from -3 to +3, holding up to 14 electrons.
Explanation:The n, l, and possible ml values for 2p and 5f sublevels are derived from the quantum numbers that define the properties of electrons in atoms. For the 2p sublevel, n is 2 (the principal quantum number indicating the second shell), l is 1 (the angular momentum quantum number corresponding to a p sublevel), and the possible ml values range from -1 to +1 (which are -1, 0, and 1), making for three possible orientations.
For the 5f sublevel, n is 5 (indicating the fifth shell), l is 3 (f sublevel), and the possible ml values range from -3 to +3 (which are -3, -2, -1, 0, 1, 2, 3), resulting in a total of seven possible orientations. Using the formula maximum number of electrons that can be in a subshell = 2(2l + 1), we can calculate that the 2p sublevel can hold a maximum of 6 electrons and the 5f sublevel can hold up to 14 electrons.
Match the following aqueous solutions with the appropriate letter from the column on the right. Assume complete dissociation of electrolytes. D 1. 0.11 m Fe(NO3)3 A. Lowest freezing point C 2. 0.18 m NaOH B. Second lowest freezing point B 3. 0.21 m FeSO4 C. Third lowest freezing point A 4. 0.38 m Glucose (nonelectrolyte) D. Highest freezing point An error has been detected in your answer. Check
Answer:
1)- 0.11 m Fe(NO₃)₃ ⇒ A- Lowest freezing point
2)- 0.18 m NaOH ⇒ D- Highest freezing point
3)- 0.21 m FeSO₄ ⇒ B- Second lowest freezing point
4)- 0.38 m Glucose ⇒ C- Third lowest freezing point
Explanation:
Freezing point depression is given by the following equation:
ΔTf= Kf x m x i
As it is a depression point (final temperature is lower than initial temperature), as higher is ΔTf, lower is the freezing point. Kf is the cryoscopic constant. For water, Kf= 1.853 K·kg/mol. At high m (molality of solute) and i (Van't Hoff factor, dissociated species), the freezing point will be low.
Kf is the same for all solution, so we can simply calculate m x i and order the solutions from high m x i (lowest freezing point) to low m x i (highest freezing point):
Fe(NO₃)₃⇒ Fe³⁺ + 3 NO₃⁻ -------> i= 1 + 3= 4m x i = 0.11 x 4 = 0.44
A) Lowest freezing point
NaOH ⇒ Na⁺ + OH⁻ -------------> i= 1+1= 2
m x i = 0.18 x 2= 0.36
D) Highest freezing point
FeSO₄ ⇒ Fe²⁺ + SO₄⁻ -------------> i= 1+1= 2m x i = 0.21 x 1= 0.42
B) Second lowest freezing point
Glucose -------------> non electrolyte : i=1m x i = 0.38 x 1 = 0.38
C) Third lowest freezing point
A fall in the hotness and coldness at which the matter freezes is called freezing point depression.
It can be calculated using:
[tex]\Delta \text{T}_{\text{f}} &= \text{K}_{\text{f}} \times \text{m} \times \text{ i}[/tex]
The initial temperature is higher than the final temperature as it is a depression point.Higher the [tex]\Delta \text{T}_{\text{f}}[/tex] lower will be the freezing point.[tex]\text{k}_{\text{f}}[/tex] is the constant for cryoscopic.When m (molality) and the i (Van't Hoff factor) are high the freezing point would be low.For all the solution [tex]\text{k}_{\text{f}}[/tex] value is constant hence, m × i can be calculated to know the order of lowest and highest freezing points.
The correct matches are:
1) 0.11 m Fe(NO₃)₃ ⇒ Option A. Lowest freezing point
Fe(NO₃)₃⇒ Fe³⁺ + 3 NO₃⁻ ⇒ i = 1 + 3 = 4m x i = 0.11 x 4 = 0.44Option A. Lowest freezing point2) 0.18 m NaOH ⇒ Option D. Highest freezing point
NaOH ⇒ Na⁺ + OH⁻ ⇒ i = 1+1 = 2m x i = 0.18 x 2= 0.36Option D. Highest freezing point3) 0.21 m FeSO₄ ⇒ Option B. Second lowest freezing point
FeSO₄ ⇒ Fe²⁺ + SO₄⁻ ⇒ i = 1+1 = 2m x i = 0.21 x 1= 0.42Option B. Second lowest freezing point4) 0.38 m Glucose ⇒ Option C. Third lowest freezing point
Glucose ⇒ non electrolyte : i = 1m x i = 0.38 x 1 = 0.38Option C. Third lowest freezing pointTo learn more about freezing point depression refer to the link:
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Niobium (Nb; Z = 41) has an anomalous ground-state electron configuration for a Group 5B(5) element: [Kr] 5s¹4d⁴. What is the expected electron configuration for elements in this group? Draw partial orbital diagrams to show how paramagnetic measurements could support niobium’s actual configuration.
Answer:
Explanation:
Niobium has an anomalous ground-state electron configuration for a Group 5 element: [Kr] 5s¹4d⁴ . IT is anomalous because in normal course , it should have been [Kr] 5s²4d³ Or [Kr] 5s⁰4d⁵ . It is so because 5s subshell
has lesser energy than 4d subshell , or half filled 4d subshell is more stable. But the stable configuration is [Kr] 5s¹4d⁴ . It is so because the energy gap between 5s and 4d is very little. So one electron of 5s² gets Transferred to 4d subshell. This paramagnetic behavior is confirmed by its dipole moment , equivalent to 5 unpaired electrons.
draw the major product, including regiochemistry, for the reaction of hex-3-yne with one equivalent of HCl. Is it an E configuration, Anti addition, Z configuration, syn addition?
Answer:
The reaction of hex-3-yne with one equivalent of HCl Is an Anti addition, see in the drawing the major product.
Explanation:
The mechanism of the reaction proceeds through a carbocation, formed in the most substituted carbon of the triple bond, in this case it is indistinct because the triple bond is in the central carbons. Therefore, it is a regioselective reaction that follows Markovnikov's rule, adding the halogen to the more substituted carbon of the alkyne.
The anti addition consists in the addition of two substituents on opposite sides of a triple bond, which gives it greater stability.
Compound A, C11H12O, which gave a negative Tollens test, was treated with LiAlH4, followed by dilute acid, to give compound B, which could be resolved into enantiomers. When optically active B was treated with CrO3 in pyridine, an optically inactive sample of A was obtained. Heating A with hydrazine in base gave hydrocarbon C, which, when heated with alkaline KMnO4, gave carboxylic acid D. Identify compounds A, B, and C.
Compound A is an optically active ketone, B is a chiral secondary alcohol, and C is an alkene formed from A by a Wolff-Kishner reduction. Acid D is a carboxylic acid crafted from the oxidation of alkene C.
This problem involves the identification of chemical compounds through a series of reactions and stereochemical considerations. We start by identifying compound A as an optically active ketone with the molecular formula C11H12O, since it gave a negative Tollens test. LiAlH4, a strong reducing agent, follows by acid treatment, produces compound B, an alcohol that can be resolved into enantiomers, suggesting that compound A must be a ketone, as LiAlH4 can reduce ketones to secondary alcohols, which can be chiral.
When compound B reacts with CrO3/pyridine, it reverts to the optically inactive ketone compound A. This suggests that compound B is a secondary alcohol that, when oxidized, returns to the original ketone without any chirality, indicating the presence of a stereocenter in B.
Heating compound A with hydrazine in base to give hydrocarbon C suggests a Wolff-Kishner reduction, which completely removes oxygen atoms from ketones or aldehydes to yield hydrocarbons. Finally, when compound C is oxidized with alkaline KMnO4 to give carboxylic acid D, this indicates that C is an alkene.
Compound A is Ketone, Compound B is chiral alcohol, Compound C is hydrocarbon, Compound D is carboxylic acid.
Let's break down the given information step by step:
1. Compound A, [tex]C_{11}H_{12}O[/tex], gave a negative Tollens test:
This suggests that compound A does not contain an aldehyde functional group. Instead, it may contain a ketone or another functional group that does not react with Tollens reagent.
2. Compound A was treated with [tex]LiAlH_4[/tex], followed by dilute acid, to give compound B, which could be resolved into enantiomers:
The reduction of a ketone with [tex]LiAlH_4[/tex] followed by hydrolysis with dilute acid converts the ketone to a chiral alcohol. Since compound B can be resolved into enantiomers, it suggests that compound A was a prochiral ketone.
3. When optically active B was treated with [tex]CrO_3[/tex] in pyridine, an optically inactive sample of A was obtained:
This reaction is a oxidation reaction known as the Jones oxidation. It converts a secondary alcohol (like B) into a ketone without affecting the optical activity. However, since an optically inactive sample of A was obtained, it suggests that compound B must have been racemic (an equal mixture of its enantiomers). This indicates that the chiral center in compound B was destroyed during the oxidation.
4. Heating A with hydrazine in base gave hydrocarbon C, which, when heated with alkaline KMnO4, gave carboxylic acid D:
Heating a ketone with hydrazine in base (Wolff-Kishner reduction) converts it into a hydrocarbon. This indicates that compound A was a ketone. Furthermore, oxidation of hydrocarbon C with alkaline [tex]KMnO_4[/tex]gives a carboxylic acid. This suggests that hydrocarbon C must have been a primary alcohol.
An atom has a diameter of 2.50 Å and the nucleus of that atom has a diameter of 9.00×10−5 Å . Determine the fraction of the volume of the atom that is taken up by the nucleus. Assume the atom and the nucleus are a sphere.
fraction of atomic volume: ?
Calculate the density of a proton, given that the mass of a proton is 1.0073 amu and the diameter of a proton is 1.72×10−15 m.
density: ? g/cm^3
1. The fraction of the atomic volume occupied by the nucleus is approximately 0.0000064 or 6.4 x 10^-6.
2. The density of a proton is approximately 5.77 x 10^20 g/cm^3.
Part 1: Fraction of atomic volume occupied by nucleus
**1. Calculate volumes of atom and nucleus:**
- Convert Å to m:
- Atom diameter: 2.50 Å * 10^-10 m/Å = 2.50 x 10^-10 m
- Nucleus diameter: 9.00 x 10^-5 Å * 10^-10 m/Å = 9.00 x 10^-15 m
- Calculate radii:
- Atom radius: 2.50 x 10^-10 m / 2 = 1.25 x 10^-10 m
- Nucleus radius: 9.00 x 10^-15 m / 2 = 4.50 x 10^-15 m
- Calculate volumes of spheres using the formula (4/3)πr³:
- Atom volume: (4/3)π * (1.25 x 10^-10 m)³ ≈ 8.18 x 10^-31 m³
- Nucleus volume: (4/3)π * (4.50 x 10^-15 m)³ ≈ 52.36 x 10^-44 m³
**2. Calculate fraction of volume occupied by nucleus:**
- Divide nucleus volume by atom volume:
- Fraction = 52.36 x 10^-44 m³ / 8.18 x 10^-31 m³ ≈ 0.0000064
Therefore, the fraction of the atomic volume occupied by the nucleus is approximately 0.0000064 or 6.4 x 10^-6.
Part 2: Density of a proton
**1. Convert mass of proton to kg:**
- 1 amu = 1.66057 x 10^-27 kg
- Proton mass: 1.0073 amu * 1.66057 x 10^-27 kg/amu ≈ 1.6726 x 10^-27 kg
**2. Calculate volume of a proton from its diameter:**
- Proton radius: 1.72 x 10^-15 m / 2 = 8.60 x 10^-16 m
- Proton volume: (4/3)π * (8.60 x 10^-16 m)³ ≈ 2.90 x 10^-45 m³
**3. Calculate density:**
- Divide proton mass by its volume:
- Density = 1.6726 x 10^-27 kg / 2.90 x 10^-45 m³ ≈ 5.77 x 10^17 kg/m³
**4. Convert density to g/cm^3:**
- 1 kg/m³ = 1000 g/cm³
- Density ≈ 5.77 x 10^17 kg/m³ * 1000 g/cm³ ≈ 5.77 x 10^20 g/cm³
Therefore, the density of a proton is approximately 5.77 x 10^20 g/cm^3.
Calcium carbonate decomposes into calcium oxide and carbon dioxide. If 530 g of calcium carbonate decomposes, how many grams of carbon dioxide gas is produced?
Answer:
233 g
Explanation:
Let's consider the following reaction.
CaCO₃ → CaO + CO₂
We can establish the following relations:
The molar mass of calcium carbonate is 100.09 g/mol.The molar ratio of calcium carbonate to carbon dioxide is 1:1.The molar mass of carbon dioxide is 44.01 g/molThe mass of carbon dioxide produced from 530 g of calcium carbonate is:
[tex]530gCaCO_{3}\frac{1molCaCO_{3}}{100.09gCaCO_{3}} ,\frac{1molCO_{2}}{1molCaCO_{3}} .\frac{44.01gCO_{2}}{1molCO_{2}} =233gCO_{2}[/tex]
233 gram of carbon dioxide gas is produced from the decomposition of calcium carbonate.
Decomposition of calcium carbonate[tex]CaCO_3\rightarrow CaO + CO_2[/tex]
From the above decomposition, we can say that the molar ratio of calcium carbonate to carbon dioxide is 1:1.
The molar mass of calcium carbonate is 100.09 g/mol.
The molar ratio of calcium carbonate to carbon dioxide is 1:1.
The molar mass of carbon dioxide is 44.01 g/mol
The mass of carbon dioxide produced from 530 g of calcium carbonate is:
[tex]{530\ gCaCO_3}\times\frac{1molCaCO_3}{100gCaCO_3} \times\frac{1molCO_2}{1molCaCO_3} \times\frac{44.01\ gCO_2}{1molCO_2} =233\ gCO_2[/tex]
So, the 233 g [tex]CO_2[/tex] will be produced.
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A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid-base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added . What is the identity of the alkali metal cation:
Li+,Na+,K+,Rb+,
or
Cs+?
The alkali metal cation in the unknown metal hydroxide that has been reacted with hydrochloric acid is Potassium (K+). The identity of the cation was determined by performing a stoichiometric calculation based on the balanced chemical reaction and the molar masses of the alkali metal hydroxide.
Explanation:This is a stoichiometry problem that requires understanding of acid-base titration reactions. In a neutralization reaction, an acid reacts with a base to form water plus a salt. Here, the hydrochloric acid (HCl) is reacting with the alkali metal hydroxide (MOH) to form water (H2O) and a salt (MCl). The balanced chemical reaction is HCl + MOH -> H2O + MCl.
The mole ratio between HCl and MOH in this reaction is 1:1. This means that for each mole of HCl used, one mole of MOH will react. From the volume (17.0 mL) and molarity (2.5 M) of HCl used, we can calculate the number of moles of HCl, which will also be the number of moles of MOH because of the 1:1 mole ratio.
mol HCl = Molarity x Volume = 2.50 mol/L x 17.0 x 10-3 L = 0.0425 mol. Hence, the number of moles of MOH = 0.0425 mol.
The molar mass of alkali metal hydroxide (MOH) is its mass divided by the number of moles. Hence, Molar mass = mass (g) / moles = 4.36 g / 0.0425 mol = 102.59 g/mol. This molar mass is closest to the molar mass of Potassium Hydroxide (KOH), which is 39.10 (K) + 15.9994 (O) + 1.00784 (H) = 56.11 g/mol. So, the alkali metal cation in the unknown metal hydroxide is K+ (Potassium).
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The provided unknown sample contains Rubidium (Rb⁺) as its alkali metal cation. This conclusion is based on titration calculations, yielding a molar mass closest to Rb.
To identify the alkali metal cation (Li⁺, Na⁺, K⁺, Rb⁺, Cs⁺) from the given sample, we need to perform a titration calculation. Here are the steps:
First, calculate the moles of HCl used in the titration:
Molarity (M) of HCl = 2.50 MVolume (V) of HCl = 17.0 mL = 0.0170 LMoles of HCl = M × V = 2.50 mol/L × 0.0170 L = 0.0425 molThe balanced equation for the reaction is:
MOH + HCl → MCl + H2O
Since the reaction is 1:1, moles of MOH = moles of HCl = 0.0425 mol
Next, calculate the molar mass of the alkali metal hydroxide (MOH):
The mass of MOH = 4.36 gMoles of MOH = 0.0425 molMolar mass of MOH = mass / moles = 4.36 g / 0.0425 mol ≈ 102.59 g/molGiven MOH is an alkali metal hydroxide, its molar mass is the sum of the molar masses of M, O, and H, which is represented as:
M + 17.01 (since the molar mass of OH is 17.01 g/mol)
Therefore, M = 102.59 - 17.01 ≈ 85.58 g/mol
Match this result with the molar masses of the alkali metals:
Li: 6.94 g/molNa: 22.99 g/molK: 39.10 g/molRb: 85.47 g/molCs: 132.91 g/molThe metal with a molar mass closest to 85.58 g/mol is Rb (Rubidium).
Therefore, the alkali metal cation is Rb⁺ (Rubidium).
Which element would you expect to be less metallic?
(a) Cs or Rn (b) Sn or Te (c) Se or Ge
Explanation:
When we move across a period from left to right then there will occur an increase in electronegativity and also there will occur an increase in non-metallic character of the elements.
As cesium (Cs) is a group 1 element and radon (Rn) is a group 18 element. Hence, cesium (Cs) is more metallic in nature than radon.
This means that radon (Rn) is less metallic than cesium (Cs).
Tin (Sn) is a group 14 element and tellurium (Te) is a group 16 element. Hence, Te is less metallic than Sn.
Selenium (Se) is a group 16 element and germanium (Ge) is a group 14 element. Therefore, selenium being more non-metallic in nature is actually less metallic than Ge.
Magnesium Oxide decomposes to produce 3.54 grams of oxygen gas. How many grams of magnesium oxide decomposed?
Explanation:
Magnesium oxide
It is MgO Its molecular mass is : 24 +16=40 g When MgO decomposes it forms = 3.54 g of oxygen gas when 40 g of MgO decomposes it forms = 16g of oxygen or we can say that : 16g of oxygen is produced when 40 g of MgO is decomposed . 1g of oxygen will be formed from =40/16g of MgO 3.54 g of oxygen will be formed = 40/16 x 3.54 =8.85g of MgOThe activation energy for the isomerization ol cyclopropane to propene is 274 kJ/mol. By what factor does the rate of this reaction increase as the temperature rises from 231 to 293 oC?
Answer:
The rate of the reaction increased by a factor of 1012.32
Explanation:
Applying Arrhenius equation
ln(k₂/k₁) = Ea/R(1/T₁ - 1/T₂)
where;
k₂/k₁ is the ratio of the rates which is the factor
Ea is the activation energy = 274 kJ/mol.
T₁ is the initial temperature = 231⁰C = 504 k
T₂ is the final temperature = 293⁰C = 566 k
R is gas constant = 8.314 J/Kmol
Substituting this values into the equation above;
ln(k₂/k₁) = 274000/8.314(1/504 - 1/566)
ln(k₂/k₁) = 32956.4589 (0.00198-0.00177)
ln(k₂/k₁) = 6.92
k₂/k₁ = exp(6.92)
k₂/k₁ = 1012.32
The rate of the reaction increased by 1012.32
Answer:
By a factor of 2.25.
Explanation:
Using the Arrhenius equations for the given conditions:
k1 = A*(exp^(-Ea/(RT1))
k2 = A*(exp^(-Ea/(RT2))
T1 = 231°C
= 231 + 273.15 K
= 574.15 K
T2 = 293°C
= 293 + 273.15 K
= 566.15 K
Ea = 274 kJ mol^-1
R= 0.008314 kJ/mol.K
Now divide the second by the first:
k2/k1 = exp^(-Ea/R * (1/T2 - (1/T1))
= 0.444
2.25k2 = k1
While mercury is very useful in barometers, mercury vapor is toxic. Given that mercury has a ΔHvap of 59.11 kJ/mol and its normal boiling point is 356.7°C, calculate the vapor pressure in mm Hg at room temperature, 25°C.
Answer:
P = 2.65 E-3 mm Hg
Explanation:
liquid-vapor equilibrium:
⇒ ec. Clausius-Clapeyron:
Ln (P2/P1) = - ΔHv/R [ (1/T2) - (1/T1) ]∴ R = 8.314 E-3 KJ/K.mol
∴ ΔHv = 59.11 KJ/mol
∴ T2 = 25°C ≅ 298 K
∴ T1 = 356.7°C = 629.7 K
normal boiling point:
∴ P = 1 atm = P1 = 101.325 KPa
vapor pressure (P2):
⇒ Ln P2 - Ln (101.325) = - (59.11 KJ/mol)/(8.314 E-3 KJ/K.mol)*[ (1/298) - (1/629.7) ]
⇒ Ln P2 - 4.618 = - (7109.694 K)*[ 1.7676 E-3 K-1 ]
⇒ Ln P2 = 4.618 - 12.567
⇒ P2 = e∧(-7.9494)
⇒ P2 = (3.5313 E-4 KPa)×(7.50062mm Hg/KPa) = 2.65 E-3 mm Hg
Draw the Lewis structure (including all lone pair electrons and any formal charges) for one of the four possible isomers of C3H9N.
The isomer I am using is propylamine, CH3 (CH2)2 NH2. How do you draw the lewis structure? Please include lone pairs and formal charges if needed.
Answer and Explanation
The isomer picked is the N-Propylamine.
It has a lone pair of electron available on the electron rich Nitrogen and no formal charge.
Since it will be hard to draw the Lewis structure in this answer format, I'll attach a picture of the Lewis structure to this answer.
The lone pair of electron is shown by the two dots on the Nitrogen atom.
The Lewis structure for propylamine is drawn by connecting a chain of three carbon atoms with the appropriate number of hydrogen atoms, and attaching the nitrogen atom to the third carbon with two of its own hydrogen atoms and a lone pair, ensuring all atoms follow the octet rule without any formal charges.
To draw the Lewis structure for propylamine (CH₃(CH₂)₂NH₂), you should follow the basic rules of drawing Lewis structures and consider the number of valence electrons that each atom has. Carbon (C) has 4 valence electrons, Hydrogen (H) has 1, and Nitrogen (N) has 5. Here's the step-by-step breakdown:
Draw a chain of three carbon atoms (the propyl group).Attach three hydrogen atoms to the first and second carbon atoms, and two hydrogens to the third carbon.Attach the nitrogen atom to the third carbon atom.Add two hydrogen atoms to the nitrogen atom.Complete the octet around nitrogen if needed by adding a lone pair of electrons.In propylamine, no formal charges are present as all the atoms have the correct number of electrons around them for neutrality. The nitrogen atom has a free lone pair and there are no pi bonds, so each bond is a single bond.
If you need to produce X-ray radiation with a wavelength of 1 Å. a. Through what voltage difference must the electron be accelerated in vacuum so that it can, upon colliding with a target, generate such a photon? (Assume that all of the electron’s energy is transferred to the photon.)
Answer:
12.4×10^3 V
Explanation:
From E=hc/wavelength= eV
The voltage becomes
V= hc/e* wavelength
V= 6.63*10^-34*3*10^8/1.6*10^-19*1*10^-10
Note that the energy of the photon is transferred to the electron. That is the basic assumption we have applied in solving this problem. The kinetic energy of the electron is equal to the product of the electron charge and the acceleration potential.
A chemistry graduate student is given 125. mL of a 1.30 M propanoic acid (HC2H,Co2) solution. Propanoic acd is a weak acid with K - 1.3 10-5. what mass of KC2H CO2 should the student dissolve in the HC2H,CO2 solution to turn it into a buffer with pH 5.02?
Answer : The mass of [tex]KC_2H_5CO_2[/tex] is, 24.5 grams
Explanation : Given,
[tex]K_a=1.3\times 10^{-5}[/tex]
pH = 5.02
Concentration of [tex]HC_2H_5CO_2[/tex] = 1.30 M
Volume of solution = 125 mL = 0.125 L
First we have to calculate the value of [tex]pK_a[/tex].
The expression used for the calculation of [tex]pK_a[/tex] is,
[tex]pK_a=-\log (K_a)[/tex]
Now put the value of [tex]K_a[/tex] in this expression, we get:
[tex]pK_a=-\log (1.3\times 10^{-5})[/tex]
[tex]pK_a=5-\log (1.3)[/tex]
[tex]pK_a=4.89[/tex]
Now we have to calculate the concentration of [tex]KC_2H_5CO_2[/tex]
Using Henderson Hesselbach equation :
[tex]pH=pK_a+\log \frac{[Salt]}{[Acid]}[/tex]
[tex]pH=pK_a+\log \frac{[KC_2H_5CO_2]}{[HC_2H_5CO_2]}[/tex]
Now put all the given values in this expression, we get:
[tex]5.02=4.89+\log (\frac{[KC_2H_5CO_2]}{1.30})[/tex]
[tex][KC_2H_5CO_2]=1.75M[/tex]
Now we have to calculate the moles of [tex]KC_2H_5CO_2[/tex]
[tex]\text{Moles of }KC_2H_5CO_2=1.75M\times 0.125L=0.219mol[/tex]
Now we have to calculate the mass of [tex]KC_2H_5CO_2[/tex]
[tex]\text{Mass of }KC_2H_5CO_2=\text{Moles of }KC_2H_5CO_2\times \text{Molar mass of }KC_2H_5CO_2[/tex]
Molar mass of [tex]KC_2H_5CO_2[/tex] = 112 g/mol
[tex]\text{Mass of }KC_2H_5CO_2=0.219mol\times 112g/mol=24.5g[/tex]
Thus, the mass of [tex]KC_2H_5CO_2[/tex] is, 24.5 grams
To find the mass of KC₂H₃CO₂ needed to create a buffer at pH 5.02, the Henderson-Hasselbalch equation is used to calculate the ratio of conjugate base to acid, then the molar mass is used to convert moles to mass, the concentration of A⁻ is approximately 1.755 M.
The question asks for the mass of potassium propanoate (KC₂H₃CO₂) needed to create a buffer with a specific pH from a solution of propanoic acid (KC₂H₃CO₂). To solve this, we apply the Henderson-Hasselbalch equation:
[tex]\[ pH = pKa + \log \left( \frac{[A^-]}{[HA]} \right) \][/tex]
Given variables:
pH = 5.02pKa = -log[tex](1.3 \times 10^{-5})[/tex][HA] = 1.30 M (concentration of propanoic acid)Rearranging the equation to solve for A⁻:
A⁻ = [tex][HA] \times 10^{(pH - pKa)}[/tex]
A⁻ = 1.755M
After calculating A⁻, it's then converted from molarity to moles given the volume of the solution. Finally, the mass of KC₂H₃CO₂ is 1.755M by multiplying the number of moles of A⁻ by its molar mass.
Lithium ions in Lithium selenide (Li2Se) have an atomic radius of 73 pm whereas the selenium ion is 184 pm. This compound is most likely to adopt a:Select the correct answer below:
a. closest-packed array with lithium ions occupying tetrahedral holes
b. closest-packed array with lithium ions occupying octahedral holes
c. body-centered cubic array with lithium ions occupying cubic holes
d. none of the above
Explanation:
Formula according to the radius ratio rule is as follows.
[tex]\frac{r_{+}}{r_{-}} = \frac{73}{184}[/tex]
= 0.397
According to the radius ratio rule, as the calculated value is 0.397 and it lies in between 0.225 to 0.414. Therefore, it means that the type of void is tetrahedral.
Thus, we can conclude that the given compound is most likely to adopt closest-packed array with lithium ions occupying tetrahedral holes.
Answer:
closest-packed array with lithium ions occupying tetrahedral holes
Explanation:
Given the small size of lithium ions and that they are present in twice the amount as selenide ions, they must occupy tetrahedral holes in a closest-packed array.
Write the charge and full ground-state electron configuration of the monatomic ion most likely to be formed by each:
(a) Al (b) S (c) Sr
Answer:
For a: The charge on the ion formed is +3
For b: The charge on the ion formed is -2
For c: The charge on the ion formed is +2
Explanation:
An ion is formed when an atom looses or gains electron.
When an atom looses electrons, it will form a positive ion known as cation.When an atom gains electrons, it will form a negative ion known as anion.For the given options:
Option a: AlAluminium is the 13th element of the periodic table having electronic configuration of [tex]1s^22s^22p^63s^23p^1[/tex]
This element will loose 3 electrons to form [tex]Al^{3+}[/tex] ion
The charge on the ion formed is +3
Option b: SSulfur is the 16th element of the periodic table having electronic configuration of [tex]1s^22s^22p^63s^23p^4[/tex]
This element will gain 2 electrons to form [tex]S^{2-}[/tex] ion
The charge on the ion formed is -2
Option c: SrStrontium is the 38th element of the periodic table having electronic configuration of [tex]1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^2[/tex]
This element will loose 2 electrons to form [tex]Sr^{2+}[/tex] ion
The charge on the ion formed is +2
An amino acid is usually more soluble in aqueous solvent at pH extremes than it is at a pH near the isolelectric point of the amino acid. (Note that this does not mean that the amino acid is insoluble at a pH near its pI.)
Which of the following statements correctly explains this phenomenon?
(Select all that apply.)
A. The neutral charge of an amino acid molecule at its isoelectric point will make the molecule hydrophobic.
B. At pH extremes, the amino acid molecules mostly carry a net charge, thus increasing their solubility in polar solvent.
C. At very low or very high pH, the amino acid molecules have increased charge, thus form more salt bonds with water solvent molecules.
D. At pH values far from the isoelectric point, individual amino acid molecules have greater kinetic energy, thus more readily stay in solution.
Amino acids are more soluble in aqueous solvent at pH extremes due to their charged nature, which increases their solubility in polar solvents. The neutral charge of an amino acid at its isoelectric point makes it hydrophobic and less soluble. At very low or very high pH, amino acids have increased charge and form more salt bonds with water, increasing their solubility.
Explanation:This phenomenon can be explained by the properties of amino acids at different pH values. At the isoelectric point (pI), the amino acid is neutral, which makes it hydrophobic and less soluble in water (option A). At pH extremes, the amino acid molecules mostly carry a net charge, which increases their solubility in polar solvents (option B). In addition, at very low or very high pH, the amino acid molecules have increased charge and form more salt bonds with water solvent molecules, further enhancing their solubility (option C).
Calculate the molality of a solution containing 17.85 g of glycerol (C3H8O3) in 87.4 g of ethanol (C2H5OH).
Answer:
Molality for the solution is 2.22 m
Explanation:
Molality is a sort of concentration. Indicated the moles of solute in 1kg of solvent. → mol/kg
Let's determine the moles of solute (mass / molar mass)
17.85 g / 92 g/mol = 0.194 moles
Let's convert the mass of solvent (g) to kg
87.4 g . 1kg / 1000 g = 0.0874 kg
Mol/kg → Molality
0.194 mol / 0.0874 kg = 2.22 m
Calculate the energies of one photon of ultraviolet (λ = 1 x 10⁻⁸ m), visible (λ = 5 x 10⁻⁷ m), and infrared (λ = 1 x 10⁴ m) light. What do the answers indicate about the relationship between the wavelength and energy of light?
Answer:
Energy of ultraviolet light is 19.878 10⁻¹⁸ JEnergy of visible light is 3.9756 X 10⁻¹⁹ JEnergy of infrared light is 19.878 X 10⁻³⁰ JThe answers indicate that wavelength is inversely proportional to the energy of light (photon)
Explanation:
Energy of photon E = hc/λ
where;
h is Planck's constant = 6.626 X 10⁻³⁴js
c is the speed of light (photon) = 3 X 10⁸ m/s
λ is the wavelength of the photon
⇒For ultraviolet ray, with wavelength λ = 1 x 10⁻⁸ m
E = (6.626 X 10⁻³⁴ X 3 X 10⁸)/ (1 x 10⁻⁸)
E = 19.878 10⁻¹⁸ J
⇒For Visible light, with wavelength λ = 5 x 10⁻⁷ m
E = (6.626 X 10⁻³⁴ X 3 X 10⁸)/ (5 x 10⁻⁷)
E = 3.9756 X 10⁻¹⁹ J
⇒For Infrared, with wavelength λ = 1 x 10⁴ m
E = (6.626 X 10⁻³⁴ X 3 X 10⁸)/ (1 x 10⁴)
E = 19.878 X 10⁻³⁰ J
From the result above, ultraviolet ray has the shortest wavelength, but it has the highest energy among other lights.
Also infrared has the highest wavelength but the least energy among other lights.
Hence, wavelength is inversely proportional to the energy of light (photon).
The energies of one photon of ultraviolet (λ = 1 x 10⁻⁸ m), visible (λ = 5 x 10⁻⁷ m), and infrared (λ = 1 x 10⁴ m) light are [tex]1.988 \times 10^{-17} \, \text{J} \),[/tex] [tex]3.98 \times 10^{-19} \, \text{J} \),[/tex] [tex]1.99 \times 10^{-30} \, \text{J} \)[/tex] respectively. The answers indicate that as the wavelength of light decreases, the energy of the photons increases.
To calculate the energy of a photon, we use the formula:
[tex]\[ E = \frac{hc}{\lambda} \][/tex]
where:
- E is the energy of the photon
- h is Planck's constant [tex](\( 6.626 \times 10^{-34} \, \text{J} \cdot \text{s} \))[/tex]
- c is the speed of light in a vacuum [tex](\( 3.00 \times 10^8 \, \text{m/s} \))[/tex]
- [tex]\( \lambda \)[/tex] is the wavelength of the photon
Let's calculate the energy for each type of light:
Ultraviolet Light (λ = 1 x 10⁻⁸ m)
[tex]\[ E_\text{UV} = \frac{6.626 \times 10^{-34} \, \text{J} \cdot \text{s} \times 3.00 \times 10^8 \, \text{m/s}}{1 \times 10^{-8} \, \text{m}} \][/tex]
Visible Light (λ = 5 x 10⁻⁷ m)
[tex]\[ E_\text{Visible} = \frac{6.626 \times 10^{-34} \, \text{J} \cdot \text{s} \times 3.00 \times 10^8 \, \text{m/s}}{5 \times 10^{-7} \, \text{m}} \][/tex]
Infrared Light (λ = 1 x 10⁴ m)
[tex]\[ E_\text{IR} = \frac{6.626 \times 10^{-34} \, \text{J} \cdot \text{s} \times 3.00 \times 10^8 \, \text{m/s}}{1 \times 10^4 \, \text{m}} \][/tex]
Let's compute these values:
1. Ultraviolet Light:
[tex]\[ E_\text{UV} = \frac{6.626 \times 10^{-34} \times 3.00 \times 10^8}{1 \times 10^{-8}} \][/tex]
[tex]\[ E_\text{UV} = \frac{19.878 \times 10^{-26}}{1 \times 10^{-8}} \][/tex]
[tex]\[ E_\text{UV} = 19.878 \times 10^{-18} \][/tex]
[tex]\[ E_\text{UV} = 1.988 \times 10^{-17} \, \text{J} \][/tex]
2. Visible Light:
[tex]\[ E_\text{Visible} = \frac{6.626 \times 10^{-34} \times 3.00 \times 10^8}{5 \times 10^{-7}} \]\[ E_\text{Visible} = \frac{19.878 \times 10^{-26}}{5 \times 10^{-7}} \]\[ E_\text{Visible} = 3.9756 \times 10^{-19} \]\[ E_\text{Visible} = 3.98 \times 10^{-19} \, \text{J} \][/tex]
3. Infrared Light:
[tex]\[ E_\text{IR} = \frac{6.626 \times 10^{-34} \times 3.00 \times 10^8}{1 \times 10^4} \]\[ E_\text{IR} = \frac{19.878 \times 10^{-26}}{1 \times 10^4} \]\[ E_\text{IR} = 1.9878 \times 10^{-30} \]\[ E_\text{IR} = 1.99 \times 10^{-30} \, \text{J} \][/tex]
Summary of Energies
- Ultraviolet Light (λ = 1 x 10⁻⁸ m): [tex]\( E_\text{UV} = 1.988 \times 10^{-17} \, \text{J} \)[/tex]
- Visible Light (λ = 5 x 10⁻⁷ m): [tex]\( E_\text{Visible} = 3.98 \times 10^{-19} \, \text{J} \)[/tex]
- Infrared Light (λ = 1 x 10⁴ m): [tex]\( E_\text{IR} = 1.99 \times 10^{-30} \, \text{J} \)[/tex]
Relationship between Wavelength and Energy
Specifically:
- Ultraviolet light has the shortest wavelength and the highest energy.
- Visible light has a moderate wavelength and moderate energy.
- Infrared light has the longest wavelength and the lowest energy.
This inverse relationship between wavelength and photon energy is consistent with the equation [tex]\( E = \frac{hc}{\lambda} \)[/tex]. As [tex]\( \lambda \) (wavelength) decreases, \( E \)[/tex] (energy) increases, and vice versa.
A chemical reaction produced 10.1 cm3 of nitrogen gas at 23 °C and 746 mmHg. What is the volume of this gas if the temperature and pressure are changed to 0 °C and 760 mmHg?
Answer:
volume of gas = 9.1436cm³
Explanation:
We will only temperature from °C to K since the conversion is done by the addition of 273 to the Celsius value.
Its not necessary to convert pressure and volume as their conversions are done by multiplication and upon division using the combined gas equation, the factors used in their conversions will cancel out.
V1 =10.1cm³ , P1 =746mmHg, T1=23°C =23+273=296k
V2 =? , P2 =760mmmHg , T2=0°C = 0+273 =273K
Using the combined gas equation to calculate for V2;
[tex]\frac{V1P1}{T1}=\frac{V2P2}{T2} \\ re-arranging, \\V2 =\frac{V1P1T2}{P2T1}[/tex]
[tex]V2 =\frac{10.1*746*273}{760*296}[/tex]
V2=9.1436cm³
When I was a boy, Uncle Wilbur let me watch as he analyzed the iron content of runoff from his banana ranch. A 25.0-mL sample was acidifi ed with nitric acid and treated with excess KSCN to form a red complex. (KSCN itself is co
Answer:
The question is incomplete as some details are missing. Here is the complete question ; When I was a boy, Uncle Wilbur let me watch as he analyzed the iron content of runoff from his banana ranch. A 25.0-mL sample was acidified with nitric acid and treated with excess KSCN to form a red complex. (KSCN itself is colorless.) The solution was then diluted to 100.0 mL and put in a variable-pathlength cell. For comparison, a 10.0-mL reference sample of 6.80 104 M Fe3 was treated with HNO3 and KSCN and diluted to 50.0 mL. The reference was placed in a cell with a 1.00-cm light path. The runoff sample exhibited the same absorbance as the reference when the pathlength of the runoff cell was 2.48 cm. What was the concentration of iron in Uncle Wilbur
Explanation:
The concept of beer Lambert Law and the dilution formula was used in solving the question. According to Beer Lambert law, as light enters through a solution that has an intensity Io, and emerges with intensity I with an assumed concentration c in mol/dm3 at a length l cm.
Mathematically from beer lambert law ; ecl =Ig (Io/I), where e is the extinction coefficient.
The attached file shows the detailed steps and appropriate substitution.
Write the charge and full ground-state electron configuration of the monatomic ion most likely to be formed by each:
(a) P (b) Mg (c) Se
Answer:
Part A:
Charge is [tex]P^{3-}[/tex]
Configuration is [tex]1s^2 2s^22p^63s^23p^6[/tex]
Part B:
Charge is [tex]Mg^{2+}[/tex]
Configuration is [tex]1s^2 2s^22p^6[/tex]
Part C:
Charge is [tex]Se^{2-}[/tex]
Configuration is [tex]1s^2 2s^22p^63s^23p^64s^23d^{10}4p^6[/tex]
Explanation:
Monatomic ions:
These ions consist of only one atom. If they have more than one atom then they are poly atomic ions.
Examples of Mono Atomic ions: [tex]Na^+, Cl^-, Ca^2^+[/tex]
Part A:
For P:
Phosphorous (P) has 15 electrons so it require 3 more electrons to stabilize itself.
Charge is [tex]P^{3-}[/tex]
Full ground-state electron configuration of the mono atomic ion:
[tex]1s^2 2s^22p^63s^23p^6[/tex]
Part B:
For Mg:
Magnesium (Mg) has 12 electrons so it requires 2 electrons to lose to achieve stable configuration.
Charge is [tex]Mg^{2+}[/tex]
Full ground-state electron configuration of the mono atomic ion:
[tex]1s^2 2s^22p^6[/tex]
Part C:
For Se:
Selenium (Se) has 34 electrons and requires two electrons to be stable.
Charge is [tex]Se^{2-}[/tex]
Full ground-state electron configuration of the mono atomic ion:
[tex]1s^2 2s^22p^63s^23p^64s^23d^{10}4p^6[/tex]
The electron configuration of atoms or ions depends on the number of electrons present.
The electron configuration refers to the arrangement of electrons in an atom or ions. Electrons are arranged in energy levels and each energy level is composed of orbitals.
The monoatomic ion most likely formed by P is P^3-. The electron configuration of this ion is 1s2 2s2 2p6 3s2 3p6. This is because P is in group 15 and attains a stable octet by gaining three electrons.
The monoatomic ion most likely formed by Mg is Mg^2+. Mg is a group 2 element and attains a stable octet by loss of two electrons. The electron configuration of this ion is 1s² 2s² 2p^6.
Se is a group 16 element, the monoatomic ion formed by Se is Se^2-. Se attains a stable octet by gain of two electrons. The electron configuration of this ion is; 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6.
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A parallel-plate capacitor is charged and then is disconnected from the battery. By what factor does the stored energy change when the plate separation is then doubled? It becomes four times larger. It becomes one-half as large. It stays the same. It becomes two times larger.
When the plate separation of a charged parallel-plate capacitor is doubled, the stored energy becomes one-half as large due to the inverse relationship between capacitance and the distance between plates.
When a parallel-plate capacitor is disconnected from a battery and the plate separation is doubled, the stored energy changes in the following manner: The stored energy becomes one-half as large. This happens because the energy (U) stored in a capacitor is given by U = (1/2)CV2, where C is the capacitance and V is the voltage across the plates. When the capacitor is disconnected from the battery, the charge Q and voltage V across the plates remain constant.
However, the capacitance C of a parallel-plate capacitor is directly proportional to the area of the plates (A) and inversely proportional to the distance (d) between them, as given by C = ε0A/d, where ε0 is the vacuum permittivity. When distance d is doubled, capacitance C is halved, therefore, the energy stored, which is proportional to C, also halves because it is dependent on the capacitance.
What is the molarity of sodium ions in a solution prepared by mixing 236 ml of 0.75 M sodium phosphate with 252.8 ml of 1.2 M sodium sulfide. Enter to 2 decimal places.
Answer:
2.33 M is the molarity of sodium ions in a solution prepared by mixing.
Explanation:
[tex]Molarity=\frac{n}{V(L)}[/tex]
n = moles of substance
V = Volume of solution in L
In, 236 ml of 0.75 M sodium phosphate :
Moles of sodium phosphate = n
Volume of sodium phosphate solution = V = 236 mL = 0.236 L(1 m L =0.001 L)
Molarity of the solution = M = 0.75 M
[tex]n=M\times V=0.75 M\times 0.236 L=0.177 mol[/tex]
Sodium phosphate = [tex]Na_3PO_4[/tex]
1 mole of sodium phosphate has 3 mol of sodium ions.
Then 0.177 moles will have = 0.177 mol × 3 = 0.531 mol
In, 252.8 ml of 1.2 M sodium sulfide:
Moles of sodium sulfide = n'
Volume of sodium sulfide solution = V' = 252.8 mL = 0.2528 L(1 m L =0.001 L)
Molarity of the solution = M' = 1.2 M
[tex]n'=M'\times V'=1.2 M\times 0.2528 L=0.30336 mol[/tex]
Sodium sulfide= [tex]Na_2S[/tex]
1 mole of sodium sulfide has 2 mol of sodium ions.
Then 0.30336 moles will have = 0.30336 mol × 2 = 0.60672 mol
After mixing both solutions:
Moles of sodium ions = 0.60672 mol + 0.531 mol = 1.13772 mol
Volume of the mixture = 0.2528 L = 0.236 L = 0.4888 L
Molarity of sodium ions:
[tex]=\frac{1.13772 mol}{0.4888 L}=2.3275 M\approx 2.33 M[/tex]
2.33 M is the molarity of sodium ions in a solution prepared by mixing.
The molarity of sodium ion, Na⁺ in the resulting solution is 2.33 M
We'll begin by calculating the number of mole of sodium ion, Na⁺ in each solution.
For Na₃PO₄:
Volume = 236 mL = 236 / 1000 = 0.236 L
Molarity = 0.75 M
Mole of Na₃PO₄ =?Mole = Molarity x Volume
Mole of Na₃PO₄ = 0.75 × 0.236
Mole of Na₃PO₄ = 0.177 moleNa₃PO₄(aq) —> 3Na⁺(aq) + PO₄³¯(aq)
From the balanced equation above,
1 mole of Na₃PO₄ contains 3 mole of Na⁺
Therefore,
0.177 mole of Na₃PO₄ will also contain = 0.177 × 3 = 0.531 mole of Na⁺
Thus, 0.531 mole of Na⁺ is present in 480 mL of 0.75 M Na₃PO₄
For Na₂S:
Volume = 252.8 mL = 252.8 / 1000 = 0.2528 L
Molarity = 1.2 M
Mole of Na₂S =?Mole = Molarity x Volume
Mole of Na₂S = 1.2 × 0.2528
Mole of Na₂S = 0.30336 moleNa₂S(aq) —> 2Na⁺(aq) + S²¯(aq)
From the balanced equation above,
1 mole of Na₂S contains 2 moles of Na⁺
Therefore,
0.30336 mole of Na₂S will contain = 0.30336 × 2 = 0.60672 mole of Na⁺
Thus, 0.60672 mole of Na⁺ is present in 252.8 mL of 1.2 M Na₂S
Next, we shall determine the total mole of Na⁺ in the resulting solution.Mole of Na⁺ in Na₃PO₄ = 0.531 mole
Mole of Na⁺ in Na₂S = 0.60672 mole
Total mole = 0.531 + 0.60672
Total mole = 1.13772 moleNext, we shall determine the total volume of the resulting solutionVolume of Na₃PO₄ = 0.236 L
Volume of Na₂S = 0.2528 L
Total volume = 0.236 + 0.2528
Total volume = 0.4888 LFinally, we shall determine the molarity of Na⁺ in the resulting solutionTotal mole = 1.13772 mole
Total volume = 0.4888 L
Molarity of Na⁺ =?Molarity = mole / Volume
Molarity of Na⁺ = 1.13772 / 0.4888
Molarity of Na⁺ = 2.33 MTherefore, the molarity of sodium ion, Na⁺ in the resulting solution is 2.33 M
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Calculate the mass of glucose C6H12O6 that contains a million ×1.0106 carbon atoms. Be sure your answer has a unit symbol if necessary, and round it to 2 significant digits.
Answer:
The mass of glucose that contains a million [tex]1.0\times 10^6[/tex] carbon atoms is [tex]4.98\times 10^{-17} g[/tex].
Explanation:
Number of carbon atoms = [tex]1.0\times 10^6 [/tex]
1 molecule of glucose has 6 carbon atoms, then [tex]1.01\times 10^6 [/tex] will be in N molecules of glucose:
[tex]N=\frac{1.0\times 10^6}{6}[/tex]molecules of glucose
1 mole = [tex]N_A=6.022\times 10^{23} molecules[/tex]
Moles of glucose = n
[tex]N=n\times N_A[/tex]
[tex]n=\frac{N}{N_A}=\frac{\frac{1.0\times 10^6}{6}}{6.022\times 10^{23}}[/tex]
[tex]n=2.768\times 10^{-19} moles[/tex]
Mass of [tex]2.768\times 10^{-19} [/tex] moles of glucose;
[tex]2.768\times 10^{-19} mol\times 180=4.9817\times 10^{-17} g\approx 4.98\times 10^{-17} g[/tex]
Calculate the mass of glucose C₆H₁₂O₆ that contains a million (1.0 × 10⁶) carbon atoms. Be sure your answer has a unit symbol if necessary, and round it to 2 significant digits.
The mass of glucose that contains a million carbon atoms is 5.04 × 10⁻⁷ g.
1 molecule of glucose contains 6 carbon atoms. The number of molecules of glucose that contain 1.0 × 10⁶ carbon atoms are:
[tex]1.0 \times 10^{6}\ C\ atoms \times \frac{1\ Glucose\ molecule}{6\ C\ atoms} = 1.7 \times 10^{5} \ Glucose\ molecule[/tex]
We will convert molecules into moles using Avogadro's number: there are 6.02 × 10²³ molecules in 1 mole of molecules.
[tex]1.7 \times 10^{5} \ molecule \times \frac{1mol}{6.02 \times 10^{23} \ molecule} = 2.8 \times 10^{-19} \ mol[/tex]
We will convert moles to mass using the molar mass of glucose (180.16 g/mol).
[tex]2.8 \times 10^{-19} \ mol \times \frac{180.16g}{1mol} =5.04 \times 10^{-7} g[/tex]
The mass of glucose that contains a million carbon atoms is 5.04 × 10⁻⁷ g.
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How many extractions are required to recover at least 99.5% of the material in the organic layer if the partition coefficient is 10 and there is 50 mL of water and ether used in each extraction?
Answer:
At least 3 three extractions are required to recover at least 99.5 % of the material in the organic layer.
Explanation:
The partition coefficient of a solute (S) soluble in two immiscible solvents is given by the following formula
[tex]K_S=\frac{[S]_2}{[S]_1}[/tex]
The lower layer is taken as an aqueous layer (1), while the upper layer is organic (2). The fraction of solute remaining in the aqueous layer is given by the following formula
[tex]q^n=(\frac{V_1}{V_1 \times KV_2})^n[/tex]
Here, n denotes the number of extraction, and q^n represents the fraction of solute remaining in aqueous solvent after n number of extraction. According to the given data, the fraction of solute remaining in the aqueous layer after multiple extractions is 0.005, i.e., q^n=0.005. Mathematically,
[tex]0.005=(\frac{50}{50 + 50\times10})^n\\\\0.005=(0.091)^n[/tex]
Taking log on both sides
[tex]log(0.005)=nlog(0.091)[/tex]
[tex]log(0.005)=nlog(0.091)\\\\-2.301=-n1.04\\n=2.21[/tex]
The above calculations show that the number of extractions should be greater than 2, i.e, at least 3, in order to achieve extraction greater than 99.5 %.
With a partition coefficient of 10 and using 50mL each of water and ether, approximately three extractions are required to recover at least 99.5% of the material in the organic layer.
Explanation:This question relates to an extraction process used in chemistry. The extraction process is governed by a partition coefficient, which is the ratio of the concentrations of a compound in the two solvents (organic layer and water in this case) at equilibrium. To calculate the number of extractions required to recover at least 99.5% of the material, we can use the formula:
Remaining fraction after n extractions = (1 - 1/(1+D))^nWhere D is the partition coefficient. By rearranging this equation, we get:
n = log(1 - desired fraction) / log (1 - 1/(1+D))Substituting the given values into the equation, we find that approximately 3 extractions would be required in order to recover at least 99.5% of the material in the organic layer.
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A certain liquid X has a normal boiling point of 118.4 °C and a boiling point elevation constant K=2.40 °С kg-mol-1. A solution is prepared by dissolving some benzamide (C7H7NO) in 150g of X. This solution boils at 120.6 °C. Calculate the mass of C7H7NO that was dissolved.Be sure your answer is rounded to the correct number of significiant digits.
Answer:
43.47 g
Explanation:
The boiling point elevation is described as:
ΔT = K * mWhere ΔT is the difference in boiling points: 120.6-118.4 = 2.2 °C
K is the boiling point elevation constant, K= 2.40 °C·kg·mol⁻¹
and m is the molality of the solution (molality = mol solute/kg solvent).
So first we calculate the molality of the solution:
ΔT = K * m2.2 °C = 2.40 °C·kg·mol⁻¹ * mm=0.917 mNow we calculate the moles of benzamide (C₇H₇NO, MW=315g/mol), using the given mass of the liquid X.
150 g ⇒ 150/1000 = 0.150 kg0.917 m = molC₇H₇NO / 0.150kgmolC₇H₇NO = 0.138 molFinally we convert moles of C₇H₇NO into grams, using its molecular weight:
0.138 molC₇H₇NO * 315g/mol = 43.47 gFinal answer:
To calculate the mass of C7H7NO dissolved in the solution, use the formula for boiling point elevation in a solution.
Explanation:
The mass of C7H7NO that was dissolved in the solution can be calculated using the formula:
ΔTb = i * K * m
Where ΔTb is the boiling point elevation, i is the van't Hoff factor (number of particles the solute dissociates into), K is the boiling point elevation constant, and m is the molality of the solution.
Substitute the given values into the equation to find the mass of C7H7NO dissolved.
How accurately can an umpire know the position of a baseball (mass = 0.142 kg) moving at 100.0 mi/h ± 1.00% (44.7 m/s ± 1.00%)?
Final answer:
The accuracy of an umpire knowing the position of a baseball depends on the speed of the baseball and the percentage uncertainty in that speed. The formula Δx = v × Δt can be used to calculate the uncertainty in the position of the baseball. For example, if the umpire measures the position of the baseball over a time interval of 1 second, the uncertainty in the position would be 44.7 meters.
Explanation:
The accuracy with which an umpire can know the position of a baseball depends on several factors, including the speed of the baseball and the percentage uncertainty in that speed.
Given that the baseball is moving at 100.0 mi/h ± 1.00% (44.7 m/s ± 1.00%), and assuming the umpire can accurately measure the speed, the uncertainty in the position of the baseball can be calculated using the formula:
Δx = v × Δt
where Δx is the uncertainty in the position, v is the velocity of the baseball, and Δt is the time interval over which the position is being measured.
For example, if the umpire measures the position of the baseball over a time interval of 1 second, the uncertainty in the position would be 44.7 m/s × 1 s = 44.7 meters.
The amino acid glycine (H2N–CH2–COOH) has pK values of 2.35 and 9.78. Indicate the structure and net charge of the molecular species that predominate at pH 2, 7, and 10. Use the following structure format and add or remove protons and charges to provide your answer.
Glycine, an amino acid, changes its structure and net charge in response to pH due to two dissociable protons. At pH 2 it's fully protonated with a net charge of +1. At pH 7, its carboxyl group loses a proton leaving the net charge to 0. By pH 10, both the carboxyl and amino group have lost protons, so the net charge is -1.
Explanation:The amino acid glycine (H2N–CH2–COOH) has two dissociable protons, one associated with its carboxyl group (pK 2.35) and one with its amino group (pK 9.78). At very low pH values, protons are abundant, meaning glycine is in its fully protonated form with a net charge of +1. Thus, at pH 2, the structure is H3N+–CH2–COOH and the net charge is +1.
At pH 7, the proton on the carboxyl group is lost, leaving the carboxylate form (COO-) and the proceed ammonium group (NH3+). Our structure therefore becomes H3N+–CH2–COO- with a net charge of zero.
Finally, at pH 10, glycine loses both of its protons. The structure now is H2N–CH2–COO- and the net charge is -1.
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